It may be to close, but my first thought was 'Intelligent Discontent'.

I also came up with:

'Brilliant Discontent' (although Brilliant I think is used as an exclamation in British slang)

'Clever Discontent'

'Thoughtful Discontent'

'Pensive Discontent' (although in the HP world it may make people think it's related to a pensieve)

'Learned Discontent' (maybe my second choice if Intelligent is too close to Intellectual)

These are all based on what I see as equivalents to the word Intellectual.

Now based on the description of what takes place...Mesmerizing Discontent, Seductive Discontent (my favorite), Enchanting Discontent, Enthralling Discontent (my second favorite),
Captivating Discontent

Don't know if any of this helps - probably too many choices, but I really like making up titles like this.